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Hybrid Multiscale Modeling of Corrosion Nanoinhibitors Transport

C. Trenado[1], D. Strauss[1,2], and M. Wittmar[2]
[1]Computational Diagnostics & Biocybernetics Unit, Saarland University Hospital, Homburg, Germany
[2]Leibniz-Institute for New Materials, Saarbrücken, Germany

Progress in coating technology has allowed for the development of free-chromate corrosion inhibitors, which are able to smartly migrate when required. In order to support the coating design, we propose a hybrid mathematical model to study the inhibitor's release by taking into account the thermodynamics and kinetics involved in the corrosion process. The proposed model is ...

Numerical Study of Microfluidic Fuel Cell Performance

A. E. Khabbazi[1], A.J. Richards[1], and M. Hoorfar[1]
[1]School of Engineering, UBC Okanagan, Kelowna, BC Canada, Canada

Using COMSOL Multiphysics 3.5, a numerical model has been developed to determine the effect of the channel geometry and electrode configuration on cell performance based on polarization curves. The Butler-Volmer equation was implemented to determine the reaction rates at the electrodes. The Conductive Media DC module is used to model the electric fields within the fuel cell.

Thermal Integration of Coupled SOFC System with a High-Performing Metal Hydride Storage

A. Mossadegh Pour[1], A. Dhira [1], R. Steinberger-Wilckensa[1]
[1]Department of Chemistry, University of Birmingham, Edgbaston, Birmingham, United Kingdom

Auxiliary Power Units can play an important role in reducing vehicle emissions, especially in diesel and kerosene driven vehicles. In conventional vehicles the electricity supply comes from a generator that is directly coupled to the propulsion engine. New generation of fuel cell APUs exclusively use Solid Oxide Fuel Cells with some developments in high temperature polymer electrolyte membranes ...

Transient Model of a Fluorine Electrolysis Cell

J. Vukasin [1], I. Crassous [1], B. Morel [1], J. Sanchez-Marcano [2], P. Namy [3]
[1] HRP, AREVA NC, France
[2] Institut Européen des Membranes - CNRS, France
[3] Simtec, France

In the nuclear fuel cycle, fluorine is produced by the electrolysis of the molten salt KF-2HF. It is a complex process to study since hydrofluoric acid and fluorine are hazardous and highly corrosive. A 3D-model of a lab-scale fluorine electrolysis cell has been developed to increase our understanding of this process, using the electric currents and the bubbly flow interfaces to simulate the ...

Using Computational Multiphysics to Optimise Channel Design for a Novel PEM Fuel Cell Stack

F. A. Daniels[1], D. J. L. Brett[1], A. R. Kucernak[2], and C. Attingre[2]
[1]University College London, London, UK
[2]Imperial College London, London, UK

Polymer electrolyte membrane (PEM) fuel cells have significant potential as a source of clean, efficient energy production. This study presents a three-dimensional, non-isothermal, fully-coupled model of a PEM fuel cell with printed circuit board current collectors. The effect of the current collector design on transport phenomena and consequent cell performance is investigated. The model ...

Effect of Channel Width on Fuel Cell Performance Using 3D Modelling

R. Pushpangadan, S. S. Dimble, and S. P. Duttagupta
IIT Bombay
Maharasthra, India

A three Dimensional model of the PEM Fuel cell is implemented using COMSOL Multiphysics and the channel width is varied to study the performance.Effect of channel width on the performance of the cell is studied by varying the width of the channel and keeping channel width to rib ratio constant at 1. Rib width is the width of the GDL area which is not covered by the channel. All other parameters ...

Kinetic Investigation of a Mechanism for Generating Microstructures on Polycrystalline Substrates Using an Electroplating Process

T. Soares[1], H. Mozaffari[2], H. Reinecke[1]
[1]Universität Freiburg, Freiburg im Breisgau, BW, Germany
[2]Hochschule Furtwangen, Tuttlingen, BW, Germany

The purpose of this study is to understand the growth mechanism of copper (Cu) films on a Cu-Zn system substrate with a pre-defined pattern. The pattern was defined by conducting a selective etching process on a two-phase polycrystalline substrate. As a result of this process, there were etched regions correspondent to beta-phase crystals and quasi non-etched regions that belong to alpha-phase ...

Effect of Pretreatments on Throwing Power of Sacrificial Metallic Coatings

J. S. Lee [1],
[1] Naval Research Laboratory, Stennis Space Center, MS, USA

Sacrificial metallic coatings (e.g. Mg-Rich Primer [MgRP]) have been evaluated for protection of aircraft aluminum alloy AA2024-T351 in marine immersion and atmospheric conditions. MgRP is designed to create a galvanic couple between the Al substratum and the Mg pigment in the primer. The Mg acts as a sacrificial anode to the more noble underlying substratum and protects local and remote ...

Simulating the Influence of the Nozzle Diameter on the Shape of Micro Geometries Generated with Jet Electrochemical Machining

A. Schubert[1][2], M. Hackert[1], and G. Meichsner[2]

[1]Chair Micromanufacturing Technology, Faculty of Mechanical Engineering, Chemnitz University of Technology, Chemnitz, Germany
[2]Fraunhofer Institute for Machine Tools and Forming Technology, Chemnitz, Germany

Jet Electrochemical Machining (Jet-ECM) is an unconventional procedure for micromachining. Based on localized anodic dissolution three-dimensional geometries and microstructured surfaces can be manufactured using Jet-ECM. COMSOL Multiphysics is used at Chemnitz UT to simulate the electric current density in the jet and the dissolution process. A mesh displacement dependent on the normal current ...

Multiphysics Simulation of an Anode-supported Micro-tubular Solid Oxide Fuel Cell (SOFC)

G. Ganzer, W. Beckert, T. Pfeifer, and A. Michaelis
Fraunhofer IKTS
Dresden, Germany

The high thermal stability and fast start-up behavior make micro-tubular solid oxide fuel cells (SOFCs) a promising alternative for small-scale, mobile power devices in the range of some Watts. To understand the transport phenomena inside a single micro-tubular SOFC, a 2-D, axi-symmetric, non-isothermal model, performed in COMSOL Multiphysics® 4.2, has been developed. Due to long current path ...